Black Stars dominated from the onset but were unable to find breakthrough as Richard Kingston kept his net safe.
Black Stars beat World XI in six-goal thriller
Two second half goals from substitute Ebenezer Assifuah and a goal from Thomas Partey and Alfred Duncan were enough to secure a win, though Sulley Muntari and Yakubu Ayigbeni scored twice in quick succession.
Atletico Madrid midfielder Thomas Partey shot the Black Stars into the lead after connecting a cross from Frank Acheampong.
Alfred Duncan gave the Black Stars a two-goal cushioning by scoring the fourth.
The game which was used to promote Peace ahead of the November general election saw a host of World stars parade at the Accra Sports Stadium.
The World XI had the likes of former Dutch international Edger David and ex-Arsenal attacker Nwankwo Kanu.
Ex-French international William Gallas and Cameroonian star Alexander Songo all featured for the World XI.
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