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The 23-year-old joined the Phobians on a free transfer after his contract with Liberty Professionals ran out months ago.
The club's official statement reads :"Hearts of Oak is delighted to announce the signing of former Liberty Professionals FC midfielder, Frederick Ansah Botchway"
Ansah was a regular feature in the Liberty Professionals setup after making his debut at the start of the 2015/16 season.
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It is however unknown if he will make the squad list for their must-win clash against Ebusua Dwarfs at the Accra Sports Stadium on Sunday.